A solution of NaHCO3 and HCl is prepared such that the total carbon concentration is 1E-3 M and the total Cl concentration is 2E-3 M. Calculate the pH and concentrations of species present. Assume that the pressure is sufficiently that any evolved CO2 remains in solution. Estimate the partial pressure of the CO2 assuming the MAB model. Plot the “apparent molality” of Cl2 in solution against the partial pressure of Cl2. The apparent molality is the sum of all Cl species in solution (Cl2 counts twice) divided by 2 (to put it on a Cl2 basis). Compare your plot to the experimental data of Whitney and Vivian (1941).39
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